Guwahati, May 1: Researchers at Indian Institute of Technology-Guwahati (IIT-G) have developed a catalyst that can release hydrogen gas from wood alcohol, with no side production of carbon dioxide.
Apart from being an easy and environmentally safe process, the method produces formic acid which is a useful industrial chemical.
This development makes methanol a promising ‘liquid organic hydrogen carrier’ (LOHC) and contributes to the concept of hydrogen-methanol economy.
Explaining the significance of the research, Akshai Kumar A.S., who led the research team and is an associate professor, department of chemistry, IIT-G said, “In methanol-reforming, in stark contrast to well-reported catalytic systems that act like Brahmastra and result in complete destruction to carbon dioxide, the current work involves a smart strategy to design pincer (crab-like) catalysts that selectively produce high-value formic acid and clean-burning hydrogen.”
The IIT-G team developed a special form of catalyst called the ‘pincer’ catalyst, which contains a central metal and a few specific organic ligands. It is called a pincer because the organic ligands are like the claws of a crab that hold the metal in place.
Owing to this special arrangement, the catalyst becomes very specific and selective. Thus, as wood alcohol is broken into hydrogen, formic acid is generated instead of carbon dioxide. The reaction takes place at 100 degrees Celsius, much lower than the temperatures required for conventional methanol-reforming.
To make the catalyst reusable, the researchers loaded the catalyst on an inert support. By this, they could reuse the catalyst over many cycles.
The details of the catalytic system have been published in the scientific journal, ACS Catalysis.
The paper has been co-authored by Vinay Arora, Eileen Yasmin,. Niharika Tanwar, Venkatesha R. Hathwar, Tushar Wagh, Sunil Dhole and Akshai Kumar A.S.
Notably, ChemDist Group of Companies is the industry collaborator in the project.
Speaking on the industrial potential of the research, Sunil Dhole, director, ChemDist Group, said, “The exciting fact about this work is that an abundantly available and cheaper organic chemical like methanol can be converted to hydrogen using a cheaper catalyst, at lower temperatures and without the emission of carbon dioxide. This technology has the potential to make significant strides towards achieving carbon neutrality.”
As the world is moving towards finding alternatives to fossil fuels, hydrogen gas continues to be the best source of clean energy generation.
Currently, hydrogen is produced either by the electrochemical splitting of water or from bio-derived chemicals such as alcohol.
IANS
